{"id":23740,"date":"2020-12-31T00:03:03","date_gmt":"2020-12-30T16:03:03","guid":{"rendered":"https:\/newsletter.sinica.edu.tw\/?p=23740"},"modified":"2021-07-19T13:50:34","modified_gmt":"2021-07-19T05:50:34","slug":"%e5%85%a8%e7%90%83%e9%a6%96%e4%be%8b%ef%bc%81%e5%90%88%e6%88%90%e7%a9%a9%e5%ae%9a%e7%9a%84%e9%9b%99%e5%8e%9f%e5%ad%90%e7%a2%b3%e5%88%86%e5%ad%90%e3%80%80%e6%9c%89%e6%9c%9b%e7%99%bc%e5%b1%95%e5%8d%8a","status":"publish","type":"post","link":"https:\/newsletter.sinica.edu.tw\/23740\/","title":{"rendered":"\u5168\u7403\u9996\u4f8b\uff01\u5408\u6210\u7a69\u5b9a\u7684\u96d9\u539f\u5b50\u78b3\u5206\u5b50\u3000\u6709\u671b\u767c\u5c55\u534a\u5c0e\u9ad4\u6750\u6599\u6280\u8853"},"content":{"rendered":"
\"\"

\uff08\u5de6\u8d77\uff09\u672c\u9662\u5316\u5b78\u6240\u6881\u5b50\u8f1d\u535a\u58eb\u5f8c\u7814\u7a76\u4eba\u54e1\u3001\u738b\u671d\u8afa\u7814\u7a76\u54e1\u3001\u5433\u9298\u5cfb\u535a\u58eb\u751f<\/p><\/div>\n

\u96d9\u539f\u5b50\u78b3 (Free C2) \u662f\u81ea\u7136\u754c\u4e2d\u6bd4\u8f03\u4e0d\u7a69\u5b9a\u7684\u5206\u5b50\uff0c\u4e00\u822c\u50c5\u80fd\u5728\u71ed\u5149\u4e2d\u85cd\u8272\u706b\u7130\u6216\u5b87\u5b99\u661f\u969b\u4e2d\u624d\u80fd\u89c0\u5bdf\u5230\u5b83\u7684\u5b58\u5728\u3002\u76f8\u8f03\u65bc\u7a69\u5b9a\u5b58\u5728\u7684\u96d9\u539f\u5b50\u5206\u5b50\u5982\u6c27\u6c23(O2)\u548c\u6c2e\u6c23(N2)\uff0c\u79d1\u5b78\u5bb6\u8f03\u7121\u6cd5\u638c\u63e1\u5176\u5316\u5b78\u548c\u7269\u7406\u6027\u8cea\uff0c\u4e26\u9032\u884c\u5f8c\u7e8c\u61c9\u7528\u3002\u672c\u9662\u5316\u5b78\u7814\u7a76\u6240\u738b\u671d\u8afa\u7814\u7a76\u54e1\u5e36\u9818\u7684\u7814\u7a76\u5718\u968a\u5728\u5e38\u6eab\u4e0b\uff0c\u6210\u529f\u5408\u6210\u7a69\u5b9a\u7684\u55ae\u914d\u4f4d\u57fa\uff08ligand\uff09(\u8a3b\u4e00)\u96d9\u539f\u5b50\u78b3\u5206\u5b50\u300cR3P\u2192C2\u300d\uff0c\u6210\u70ba\u5168\u7403\u9996\u4f8b\uff0c\u672a\u4f86\u6709\u671b\u767c\u5c55\u77f3\u58a8\u70ef\u3001\u77fd\u3001\u937a\u7b49\u534a\u5c0e\u9ad4\u6750\u6599\u6280\u8853\u3002\u6700\u65b0\u7814\u7a76\u5df2\u65bc11\u670830\u65e5\u767b\u4e0a\u570b\u969b\u671f\u520a\u300a\u81ea\u7136-\u5316\u5b78\u300b\uff08Nature Chemistry\uff09\u3002<\/p>\n

\u914d\u4f4d\u57fa\u5982\u540c\u4e2d\u5fc3\u539f\u5b50\u7684\u8863\u670d\uff0c\u53ef\u4ee5\u4f7f\u4e0d\u53ef\u898b\u3001\u4e0d\u7a69\u5b9a\u7684\u5206\u5b50\u73fe\u5f62\u3002\u914d\u4f4d\u57fa\u8d8a\u5c11\uff0c\u5206\u5b50\u7684\u6027\u8cea\u8d8a\u7c21\u55ae\u4e7e\u6de8\uff0c\u5f8c\u7e8c\u61c9\u7528\u4e5f\u66f4\u80fd\u6392\u9664\u5176\u4ed6\u56e0\u7d20\u3002\u56e0\u6b64\uff0c\u70ba\u4e86\u8981\u7a69\u5b9a\u4e2d\u5fc3\u539f\u5b50\uff0c\u901a\u5e38\u9700\u8981\u91cf\u8eab\u6253\u9020\u8863\u670d\u3002\u738b\u671d\u8afa\u7814\u7a76\u54e1\u89e3\u91cb\uff0c\u300c\u904e\u53bb\u7814\u7a76\u5e6b\u96d9\u539f\u5b50\u78b3\u7a7f\u7684\u8863\u670d\u6bd4\u8f03\u591a\u4ef6\uff0c\u6211\u5011\u9019\u6b21\u4e00\u4ef6\u641e\u5b9a\u300d\u3002<\/p>\n

\u904e\u5f80\u7814\u7a76\u66fe\u5229\u7528\u7406\u8ad6\u6a21\u64ec\u6f14\u7b97\u96d9\u539f\u5b50\u78b3\u7684\u7d50\u69cb\uff0c\u4e26\u66fe\u4f7f\u7528\u904e\u4e8c\u500b\u4ee5\u4e0a\u7684\u914d\u4f4d\u57fa\u4ee5\u7a69\u5b9a\u96d9\u539f\u5b50\u78b3\uff0c\u4f46\u5408\u6210\u51fa\u4f86\u7684\u5206\u5b50\u7684\u5316\u5b78\u548c\u7269\u7406\u6027\u8cea\u76f8\u5c0d\u8907\u96dc\u3002\u6b64\u6b21\u738b\u671d\u8afa\u7814\u7a76\u5718\u968a\u7d42\u65bc\u5e6b\u96d9\u539f\u5b50\u78b3\u627e\u5230\u53ef\u4ee5\u300c\u55ae\u4e00\u300d\u7a69\u5b9a\u4ea4\u5f80\u7684\u5c0d\u8c61R3P\u3002\u7814\u7a76\u5718\u968a\u5229\u7528\u5c08\u696d\u5316\u5b78\u6280\u8853\u6210\u529f\u5408\u6210\u5e38\u6eab\u7a69\u5b9a\u7684\u65b0\u5206\u5b50R3P\u2192C2\uff0c\u4e0d\u50c5\u95e1\u91cb\u4e86\u5316\u5b78\u7d50\u69cb\u548c\u96fb\u5b50\u7d44\u614b\u7684\u95dc\u4fc2\uff0c\u4e5f\u89e3\u958b\u5316\u5b78\u754c\u4e00\u76f4\u4ee5\u4f86\u5404\u81ea\u8868\u8ff0\u96d9\u539f\u5b50\u78b3\u5316\u5408\u7269\u548c\u96d9\u539f\u5b50\u78b3\u6027\u8cea\u7684\u8a8d\u77e5\u5dee\u7570\u3002<\/p>\n

\u6b64\u5916\uff0c\u7814\u7a76\u5718\u968a\u4e5f\u5206\u6790\u65b0\u5206\u5b50 R3P\u2192C2 \u7684\u7d50\u69cb\uff0c\u4e26\u8207\u5fb7\u570b\u99ac\u723e\u5821\u5927\u5b78\u7406\u8ad6\u8a08\u7b97\u5c08\u5bb6Gernot Frenking\u6559\u6388\u548c\u4e2d\u570b\u5357\u4eac\u5de5\u696d\u5927\u5b78\u7684Lili Zhao\u6559\u6388\u8de8\u570b\u5408\u4f5c\u3002\u63a1\u7528\u5148\u9032\u7684\u80fd\u91cf\u5206\u89e3\u5206\u6790\uff08Energy Decomposition Analysis, EDA\uff09\u7684\u8a08\u7b97\u6280\u8853\uff0c\u6df1\u5165\u63a2\u8a0e\u5176\u7d50\u69cb\u7279\u6027\u3002\u5be6\u9a57\u8b49\u5be6\uff0cR3P\u2192C2\u5728 C2\u90e8\u5206\u7684\u5169\u500b\u78b3\u539f\u5b50\u7686\u6709\u610f\u60f3\u4e0d\u5230\u7684\u53cd\u61c9\u6d3b\u6027\uff0c\u6b64\u767c\u73fe\u6709\u52a9\u767c\u5c55\u78b3\u3001\u77fd\u3001\u937a\u7b49\u78b3\u65cf(\u8a3b\u4e8c)\u4e4b\u65b0\u578b\u614b\u5316\u5b78\u53cd\u61c9\uff0c\u4e26\u61c9\u7528\u65bc\u50ac\u5316\u53cd\u61c9\u3002\u672a\u4f86\u6b64\u5206\u5b50\u4e5f\u53ef\u5ef6\u4f38\u767c\u5c55\u65b0\u578b\u5316\u5b78\u54c1\u53ca\u77f3\u58a8\u70ef\u3001\u77fd\u3001\u937a\u7b49\u76f8\u95dc\u534a\u5c0e\u9ad4\u6750\u6599\u958b\u767c\u3002<\/p>\n

\u672c\u8ad6\u6587\u7b2c\u4e00\u4f5c\u8005\u70ba\u672c\u9662\u5316\u5b78\u6240\u6881\u5b50\u8f1d\u535a\u58eb\u5f8c\u7814\u7a76\u4eba\u54e1\uff0c\u7814\u7a76\u5718\u968a\u5305\u62ec\u672c\u9662\u5316\u5b78\u6240\u5433\u9298\u5cfb\u535a\u58eb\u751f\u3001\u901a\u8a0a\u4f5c\u8005\u738b\u671d\u8afa\u7814\u7a76\u54e1\u3002\u7d93\u8cbb\u4f86\u6e90\u70ba\u672c\u9662\u6df1\u8015\u8a08\u756b\u53ca\u79d1\u6280\u90e8\u7d93\u8cbb\u3002
\n\u8ad6\u6587\u5168\u6587\uff1a\u3008Isolable dicarbon stabilized by a single phosphine ligand\u3009https:\/www.nature.com\/articles\/s41557-020-00579-w<\/a><\/p>\n

\n

(\u8a3b\u4e00)\u914d\u4f4d\u57fa\uff1a\u5316\u5b78\u540d\u8a5e\u3002\u53ef\u548c\u4e2d\u5fc3\u539f\u5b50\uff08\u91d1\u5c6c\u6216\u985e\u91d1\u5c6c\uff09\u7522\u751f\u9375\u7d50\u7684\u539f\u5b50\u3001\u5206\u5b50\u6216\u96e2\u5b50\u3002\u55ae\u914d\u4f4d\u57fa\u6307\u7684\u662f\uff0c\u50c5\u4e00\u8655\u8207\u4e2d\u5fc3\u539f\u5b50\u7d50\u5408\u7684\u539f\u5b50\u3001\u5206\u5b50\u6216\u96e2\u5b50\u3002<\/p>\n

(\u8a3b\u4e8c)\u78b3\u65cf\uff1a\u7b2c14\u65cf\uff0c\u5305\u542b\u78b3\uff08C\uff09\u3001\u77fd\uff08Si\uff09\u3001\u937a\uff08Ge\uff09\u3001\u932b\uff08Sn\uff09\u3001\u925b\uff08Pb\uff09\u3001\u9207\uff08Fl\uff09\u7b49\u5316\u5b78\u5143\u7d20\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u96d9\u539f\u5b50\u78b3 (Free C2) \u662f\u81ea\u7136\u754c\u4e2d\u6bd4\u8f03\u4e0d\u7a69\u5b9a\u7684\u5206\u5b50\uff0c\u4e00\u822c\u50c5\u80fd\u5728\u71ed\u5149\u4e2d\u85cd\u8272\u706b\u7130\u6216\u5b87\u5b99\u661f\u969b\u4e2d\u624d\u80fd\u89c0\u5bdf\u5230\u5b83\u7684\u5b58 […]<\/p>\n","protected":false},"author":1,"featured_media":23741,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_et_pb_use_builder":"","_et_pb_old_content":"","_et_gb_content_width":"","footnotes":""},"categories":[4],"tags":[],"acf":[],"_links":{"self":[{"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/posts\/23740"}],"collection":[{"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/comments?post=23740"}],"version-history":[{"count":1,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/posts\/23740\/revisions"}],"predecessor-version":[{"id":23742,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/posts\/23740\/revisions\/23742"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/media\/23741"}],"wp:attachment":[{"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/media?parent=23740"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/categories?post=23740"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/tags?post=23740"}],"curies":[{"name":"wp","href":"https:\/api.w.org\/{rel}","templated":true}]}}