{"id":32106,"date":"2023-08-10T00:11:12","date_gmt":"2023-08-09T16:11:12","guid":{"rendered":"https:\/newsletter.sinica.edu.tw\/?p=32106"},"modified":"2023-08-10T00:42:22","modified_gmt":"2023-08-09T16:42:22","slug":"%e3%80%90%e5%b0%88%e6%ac%84%e3%80%91%e7%a5%9e%e5%a5%87%e7%9a%84%e9%9d%9e%e5%85%ab%e9%9a%85%e9%ab%94%e7%a2%b3%e9%85%8d%e4%bd%8d%e5%9f%ba","status":"publish","type":"post","link":"https:\/newsletter.sinica.edu.tw\/32106\/","title":{"rendered":"\u3010\u5c08\u6b04\u3011\u795e\u5947\u7684\u975e\u516b\u9685\u9ad4\u78b3\u914d\u4f4d\u57fa"},"content":{"rendered":"
\n
\n\t\t\t\t\t\"\u738b\u671d\u8afa\u7814\u7a76\u54e1\uff08\u672c\u9662\u5316\u5b78\u7814\u7a76\u6240\uff09\"\n\t\t\t\t<\/div><\/p>\n
\n\t\t\t\t\t

\u738b\u671d\u8afa\u7814\u7a76\u54e1\uff08\u672c\u9662\u5316\u5b78\u7814\u7a76\u6240\uff09<\/p>\n

\u7814\u7a76\u8208\u8da3<\/strong> \n\u5229\u7528\u904e\u6e21\u91d1\u5c6c\u932f\u5408\u7269\u6216\u6709\u6a5f\u91d1\u5c6c\u70ba\u6750\u6599\uff0c\u5c0b\u627e\u5176\u4f5c\u7528\u65bc\u50ac\u5316\u53cd\u61c9\u4e2d\u5d84\u65b0\u7684\u61c9\u7528\uff0c\u4ee5\u958b\u767c\u51fa\u65b0\u7684\u50ac\u5316\u5316\u5b78\uff0c\u4e26\u6709\u52a9\u65bc\u7da0\u8272\u5316\u5b78\u767c\u5c55\u3002\u9019\u4e9b\u7814\u7a76\u5728\uff08i\uff09\u7528\u65bc\u7da0\u8272\u5206\u5b50\u5408\u6210\u7684 C-H\/C-O \u9375\u6d3b\u5316\u3001\uff08ii\uff09\u975e\u516b\u4f4d\u78b3\u7269\u7a2e\uff08\u5361\u8cd3\u3001\u78b3\u548c\u78b3\u4e8c\u5361\u8cd3\uff09\u7684\u5316\u5b78\u548c\uff08iii\uff09\u5c0f\u5206\u5b50\u6d3b\u5316\u65b9\u9762\u5e36\u4f86\u4e86\u65b0\u7684\u95dc\u9375\u5275\u65b0\u3002<\/p>\n

\u7c21\u6b77<\/strong> \n2015- \u8fc4\u4eca \u672c\u9662\u5316\u5b78\u6240 \u7814\u7a76\u54e1  \n2017- \u8fc4\u4eca \u81fa\u5927\u5316\u5b78\u7cfb\u5408\u8058\u6559\u6388  \n2021- \u8fc4\u4eca \u672c\u9662\u5316\u5b78\u6240\u526f\u6240\u9577 <\/p>\n

\u69ae\u8b7d<\/strong> \n2021 \u69ae\u7372\u4e2d\u592e\u7814\u7a76\u9662\u7279\u512a\u5b78\u8853\u7814\u7a76\u734e\u91d1  \n2019 \u79d1\u6280\u90e8\u5091\u51fa\u7814\u7a76\u734e\n\t\t\t\t<\/div>

<\/div>\n<\/div>\n

\u78b3\uff08carbon\uff09\u662f\u4e00\u7a2e\u5728\u6211\u5011\u751f\u6d3b\u5468\u906d\u96a8\u8655\u53ef\u898b\u7684\u5316\u5b78\u5143\u7d20\uff0c\u5176\u5143\u7d20\u7b26\u865f\u70ba C\uff0c\u5b83\u4e5f\u662f\u6709\u6a5f\u548c\u7121\u6a5f\u5316\u5b78\u4e2d\u975e\u5e38\u91cd\u8981\u7684\u7d44\u6210\u4efd\u5b50\uff1b\u5728\u6709\u6a5f\u5316\u5b78\u9818\u57df\u88e1\u6240\u63a2\u8a0e\u7684\u6709\u6a5f\u5206\u5b50\uff0cC \u662f\u5fc5\u8981\u7684\u7d44\u6210\u5143\u7d20\uff0c\u4f8b\u5982\ufe30\u5728\u4e00\u500b\u8461\u8404\u7cd6\uff08C6<\/sub>H12<\/sub>O6<\/sub>\uff09\u5206\u5b50\u4e2d\u542b\u6709\u516d\u500b C \u539f\u5b50\uff0c\u4e00\u500b\u4e59\u9187\uff08C2<\/sub>H5<\/sub>OH\uff09\u5206\u5b50\u4e2d\u542b\u6709\u4e8c\u500b C \u539f\u5b50\uff1b\u5728\u7121\u6a5f\u5316\u5b78\u9818\u57df\u4e2d\u6240\u63a2\u8a0e\u7684\u5143\u7d20\u78b3\u7684\u540c\u7d20\u7570\u5f62\u9ad4\u4e2d\uff0c\u6700\u5e38\u898b\u7684\u5305\u62ec\u947d\u77f3\u3001\u77f3\u58a8\u53ca\u4e00\u4e9b\u7121\u5b9a\u5f62\u78b3\uff0c\u7531\u9019\u4e9b\u540c\u7d20\u7570\u5f62\u9ad4\u7684\u5916\u89c0\uff0c\u5b8c\u5168\u7121\u6cd5\u60f3\u50cf\u5b83\u5011\u662f\u7531\u540c\u4e00\u500b\u5143\u7d20\u6240\u7d44\u6210\uff08\u900f\u660e\u7684\u947d\u77f3\u8207\u9ed1\u8272\u7684\u77f3\u58a8\uff09\uff0c\u56e0\u6b64\uff0c\u78b3\u662f\u975e\u5e38\u795e\u5947\u7684\u5143\u7d20\u4e4b\u4e00\u3002<\/p>\n

\u96d9\u539f\u5b50\u78b3\uff08C2<\/sub>\uff09\u662f\u4e00\u7a2e\u5177\u6709\u78b3 – \u78b3\u9375\u7684\u6700\u5c0f\u96d9\u539f\u5b50\u5206\u5b50\uff0c\u4e00\u822c\u50c5\u80fd\u5728\u71ed\u5149\u4e2d\u85cd\u8272\u706b\u7130\u6216\u5b87\u5b99\u661f\u969b\u4e2d\u624d\u80fd\u89c0\u5bdf\u5230\u5b83\u7684\u5b58\u5728\uff0c\u76f8\u8f03\u65bc\u81ea\u7136\u754c\u4e2d\u7a69\u5b9a\u5b58\u5728\u7684\u96d9\u539f\u5b50\u5206\u5b50\uff0c\u4f8b\u5982\u6c27\u6c23\uff08O2<\/sub>\uff09\u548c\u6c2e\u6c23\uff08N2<\/sub>\uff09\uff0c\u96d9\u539f\u5b50\u78b3\u5e38\u5448\u73fe\u4e0d\u7a69\u5b9a\u7684\u72c0\u614b\uff0c\u7121\u6cd5\u78ba\u5be6\u5f97\u77e5\u5176\u5316\u5b78\u548c\u7269\u7406\u6027\u8cea\u3002\u904e\u5f80\u7814\u7a76\u66fe\u5229\u7528\u7406\u8ad6\u6a21\u64ec\u6f14\u7b97\u96d9\u539f\u5b50\u78b3\u7684\u7d50\u69cb\uff0c\u4e26\u66fe\u4f7f\u7528\u4e0d\u540c\u914d\u4f4d\u57fa\u7a69\u5b9a\u96d9\u539f\u5b50\u78b3\uff0c\u4f46\u90fd\u672a\u898b\u986f\u8457\u7684\u6210\u6548\uff08\u5716\u4e00 (a)\uff09\uff3b1\uff3d<\/sup>\uff0c\u672c\u7814\u7a76\u5718\u968a\u8fd1\u4f86\u5229\u7528\u5c08\u696d\u5316\u5b78\u6280\u8853\uff0c\u6210\u529f\u5408\u6210\u5e38\u6eab\u7a69\u5b9a\u7684\u55ae\u914d\u4f4d\u57fa\u96d9\u539f\u5b50\u78b3\u5206\u5b50 R3<\/sub>P \u2192 C2<\/sub>\uff0c\u4e0d\u50c5\u95e1\u91cb\u4e86\u5316\u5b78\u7d50\u69cb\u548c\u96fb\u5b50\u7d44\u614b\u7684\u95dc\u4fc2\uff0c\u4e5f\u89e3\u958b\u5316\u5b78\u754c\u4e00\u76f4\u4ee5\u4f86\u5404\u81ea\u8868\u8ff0\u96d9\u539f\u5b50\u78b3\u5316\u5408\u7269\u548c\u96d9\u539f\u5b50\u78b3\u6027\u8cea\u7684\u8a8d\u77e5\u5dee\u7570\u3002<\/p>\n

\u6b64\u5916\uff0c\u6211\u5011\u4e5f\u8207\u5fb7\u570b\u99ac\u723e\u5821\u5927\u5b78\u7406\u8ad6\u8a08\u7b97\u5c08\u5bb6 Frenking \u6559\u6388\u548c\u5357\u4eac\u5de5\u696d\u5927\u5b78\u7684\u8d99\u8389\u8389\u6559\u6388\u8de8\u570b\u5408\u4f5c\uff0c\u63a1\u7528\u81ea\u7136\u9375\u8ecc\u9053\uff08Natural bond orbital, NBO\uff09\u7406\u8ad6\u5206\u6790\u53ca\u5148\u9032\u7684\u80fd\u91cf\u5206\u89e3\u5206\u6790\uff08Energy Decomposition Analysis, EDA\uff09\u7684\u8a08\u7b97\u6280\u8853\uff0c\u6df1\u5165\u63a2\u8a0e\u5176\u7d50\u69cb\u7279\u6027\u3002\u5be6\u9a57\u8b49\u5be6\uff0cR3<\/sub>P \u2192 C2<\/sub> \u5728 C2<\/sub> \u90e8\u5206\u7684\u5169\u500b\u78b3\u539f\u5b50\u7686\u6709\u610f\u60f3\u4e0d\u5230\u7684\u53cd\u61c9\u6d3b\u6027\uff0c\u5176\u5177\u6709\u5f88\u5f37\u7684 \u03c3- \u4e88\u9ad4\u80fd\u529b\uff08\u5f37\u65bc\u78b3\u70ef (carbene)\uff09\u8207\u7a0d\u5f31\u7684 \u03c0- \u53d7\u9ad4\u7279\u6027\uff0c\u4ea6\u5373\u5176\u53ef\u4f5c\u70ba\u4e00\u7a2e\u65b0\u7684\u985e\u78b3\u70ef\u914d\u4f4d\u57fa\uff08\u5716\u4e00 (b)\uff09\uff3b2\uff3d<\/sup>\u3002\u6b64\u5916\uff0c\u85c9\u7531 Suzuki-Miyaura \u4ea4\u53c9\u8026\u5408\u53cd\u61c9\u8207\u919b\u57fa\u548c\u7094\u57fa\u7684\u9084\u539f\u5076\u806f\u5be6\u9a57\uff0c\u53ef\u4ee5\u5145\u5206\u8b49\u660e R3<\/sub>P \u2192 C2<\/sub> \u65bc\u50ac\u5316\u53cd\u61c9\u4e2d\u6240\u5177\u6709\u7684\u6548\u7528\uff0c\u5176\u4e2d\u65bc\u9084\u539f\u5076\u806f\u53cd\u61c9\u7684\u7d30\u90e8\u63a2\u8a0e\u4e2d\uff0c\u767c\u73fe R3<\/sub>P \u2192 C2<\/sub> \u8207\u91d1\u5c6c\u932f\u5408\u7269\u7684\u4e8c\u6b21\u4ea4\u4e92\u4f5c\u7528\u5c0d\u65bc\u50ac\u5316\u7cfb\u7d71\u81f3\u95dc\u91cd\u8981\uff08\u5716\u4e00 (c)\uff09\uff3b3\uff3d<\/sup>\u3002<\/p>\n

 <\/p>\n

\"\u3010\u5c08\u6b04\u3011\u795e\u5947\u7684\u975e\u516b\u9685\u9ad4\u78b3\u914d\u4f4d\u57fa\"

\u25b2\u5716\u4e00\uff1a(a) \u904e\u53bb\u7814\u7a76\u4e2d\u95dc\u65bc\u7a69\u5b9a\u96d9\u539f\u5b50\u78b3\u7684\u65b9\u6cd5\uff1b(b) \u672c\u5be6\u9a57\u5ba4\u7814\u7a76\u5718\u968a\u6210\u529f\u4f7f\u7528\u55ae\u4e00\u81a6\u5316\u7269\u914d\u4f4d\u57fa\u7a69\u5b9a\u96d9\u539f\u5b50\u78b3\u5206\u5b50\u7d50\u69cb\uff08R3<\/sub>P \u2192 C2<\/sub>\uff09\uff1b(c) \u5c07 R3<\/sub>P \u2192 C2<\/sub> \u4f5c\u70ba\u904e\u6e21\u91d1\u5c6c\u50ac\u5316\u53cd\u61c9\u4e2d\u7684\u914d\u4f4d\u57fa\u3002<\/p><\/div>\n

 <\/p>\n

\u8fd1\u5e7e\u5341\u5e74\u4f86\uff0c\u5728\u6709\u6a5f\u91d1\u5c6c\u5316\u5b78\u53ca\u7406\u8ad6\u5316\u5b78\u7814\u7a76\u9818\u57df\uff0c\u5c0d\u65bc\u5177\u6709\u975e\u516b\u9685\u9ad4\u96fb\u5b50\u69cb\u5f62\u7684\u78b3\u914d\u4f4d\u57fa\u4e4b\u7814\u7a76\u5341\u5206\u6d3b\u8e8d\uff0c\u9019\u4e9b\u914d\u4f4d\u57fa\u9664\u4e86\u81ea\u7531\u57fa\uff08radical\uff09\u3001\u5361\u62dc\uff08carbyne\uff09\u3001\u78b3\u70ef\u53ca\u524d\u8ff0\u7684\u985e\u78b3\u70ef R3<\/sub>P \u2192 C2<\/sub> \u4e4b\u5916\uff0c\u9084\u6709\u53e6\u4e00\u7a2e\u7368\u7279\u7684\u5361\u672c\uff08carbone\uff09\u5316\u5408\u7269 CL2<\/sub>\uff0c\u5b83\u662f\u5229\u7528\u5169\u500b\u914d\u4f4d\u57fa L \u53bb\u7a69\u5b9a\u5177\u6709\u5169\u5c0d\u5b64\u96fb\u5b50\u5c0d\u7684\u96f6\u50f9\u78b3\u539f\u5b50\u3002\u6700\u65e9\u88ab\u767c\u73fe\u4e26\u63a2\u8a0e\u7684\u5361\u672c\uff0c\u662f\u5229\u7528\u4e09\u82ef\u57fa\u81a6\uff08triphenyl phosphine, PPh3<\/sub>\uff09\u4f5c\u70ba\u914d\u4f4d\u57fa L \u7684\u540c\u78b3\u96d9\u81a6\u70f7\uff08carbodiphosphorane, CDP\uff09\uff3b4\uff3d<\/sup>\uff0c\u5176\u4e2d\u5fc3\u78f7\u78b3\u78f7\uff08PCP\uff09\u7684\u7d50\u69cb\u5728\u8ecc\u57df\u7684\u6df7\u6210\u4e0a\uff0c\u660e\u986f\u6703\u6bd4\u78b3\u78b3\u78b3\uff08CCC\uff09\u7684\u7d50\u69cb\u5dee\uff0c\u70ba\u4e86\u767c\u5c55\u65b0\u578b\u614b\u7684\u78b3\u78b3\u78b3\u5361\u672c\u5316\u5408\u7269\uff0c\u5fb7\u570b\u99ac\u723e\u5821\u5927\u5b78\u7684 Frenking \u6559\u6388\u65bc\u897f\u5143 2007 \u5e74\u63d0\u51fa\u4ee5\u542b\u6c2e\u96dc\u74b0\u78b3\u70ef\uff08N-heterocyclic carbene, NHC\uff09\u4f5c\u70ba\u914d\u4f4d\u57fa L \u53bb\u7a69\u5b9a\u96f6\u50f9\u78b3\u539f\u5b50\uff0c\u4e26\u5229\u7528\u7406\u8ad6\u8a08\u7b97\u5f97\u51fa\u5176\u7d50\u69cb\u53ca\u96fb\u5b50\u6027\u8cea\uff0c\u540c\u6642\u5c07\u5176\u547d\u540d\u70ba\u540c\u78b3\u96d9\u78b3\u70ef\uff08carbodicarbene, CDC\uff09\uff3b5\uff3d<\/sup>\uff1b\u9694\u5e74\uff0c\u7f8e\u570b\u52a0\u5dde\u5927\u5b78\u6cb3\u6ff1\u5206\u6821\u7684 Bertrand \u6559\u6388\u7814\u7a76\u5718\u968a\u6210\u529f\u5408\u6210\u51fa\u7b2c\u4e00\u500b\u540c\u78b3\u96d9\u78b3\u70ef\u5316\u5408\u7269\uff0c\u4e26\u4e14\u5f97\u5230\u6676\u9ad4\u8b49\u5be6\u5176\u7d50\u69cb\uff0c\u4e14\u7d50\u69cb\u6578\u64da\u8207 Frenking \u6559\u6388\u7406\u8ad6\u8a08\u7b97\u6240\u5f97\u5230\u7684\u6578\u64da\u975e\u5e38\u76f8\u8fd1\uff0c\u4f46\u662f\u6b64\u5316\u5408\u7269\u5728\u6709\u6a5f\u6eb6\u5291\u4e2d\u7684\u6eb6\u89e3\u5ea6\u8f03\u5dee\uff0c\u76f4\u63a5\u5f71\u97ff\u5176\u53cd\u61c9\u6027\uff3b6\uff3d<\/sup>\u3002\u672c\u5be6\u9a57\u5ba4\u70ba\u4e86\u6539\u5584\u6b64\u7f3a\u9ede\uff0c\u56e0\u6b64\u5c0d Bertrand \u6559\u6388\u767c\u8868\u7684\u5316\u5408\u7269\u9032\u884c\u7d50\u69cb\u4fee\u6b63\uff0c\u7531\u65bc\u53d6\u4ee3\u57fa\u7684\u78b3\u6578\u589e\u52a0\uff0c\u56e0\u6b64\u5927\u5927\u63d0\u5347\u5176\u6eb6\u89e3\u5ea6\uff0c\u6539\u5584\u5176\u5728\u6709\u6a5f\u6eb6\u5291\u4e2d\u53cd\u61c9\u6027\u7684\u554f\u984c\uff08\u5716\u4e8c(a)\uff09\uff3b7\uff3d<\/sup>\u3002<\/p>\n

\u96a8\u5f8c\uff0c\u672c\u5be6\u9a57\u5ba4\u5229\u7528\u6b64\u540c\u78b3\u96d9\u78b3\u70ef\u914d\u4f4d\u57fa\u8207\u787c\u70f7\uff08BH3<\/sub>-THF\uff09\u53cd\u61c9\uff0c\u610f\u5916\u5f97\u5230\u4e09\u914d\u4f4d\u96d9\u967d\u96e2\u5b50\u787c\u6c2b\u932f\u5408\u7269\uff0c\u7136\u800c\uff0c\u4e00\u822c\u7684\u542b\u6c2e\u96dc\u74b0\u78b3\u70ef\u8207\u787c\u70f7\u53cd\u61c9\u4e0d\u6703\u5f97\u5230\u5982\u6b64\u7279\u5225\u7684\u7522\u7269\u3002\u5f9e\u6676\u9ad4\u7d50\u69cb\u4e2d\u53ef\u4ee5\u767c\u73fe\u5176\u5305\u542b\u4e00\u500b\u96d9\u967d\u96e2\u5b50\u787c\u6c2b\u932f\u5408\u7269\u548c\u5169\u500b BH4- \u9670\u96e2\u5b50\uff0c\u787c\u539f\u5b50\u8207\u5169\u500b\u540c\u78b3\u96d9\u78b3\u70ef\u53ca\u6c2b\u5316\u7269\u5f62\u6210\u5e73\u9762\u4e09\u89d2\u5f62\u7d50\u69cb\uff0c\u800c\u787c\u78b3\u9375\u7684\u9375\u9577\u70ba 1.534(7)\u548c 1.523(7) \u00c5\uff0c\u4ecb\u65bc\u787c\u78b3\u55ae\u9375\u8207\u96d9\u9375\u9375\u9577\u4e4b\u9593\u3002\u70ba\u4e86\u66f4\u9032\u4e00\u6b65\u77ad\u89e3\u96d9\u967d\u96e2\u5b50\u787c\u6c2b\u932f\u5408\u7269\u7684\u96fb\u5b50\u6027\u8cea\uff0c\u6211\u5011\u5229\u7528\u7406\u8ad6\u8a08\u7b97\uff08B3LYP\/6-31-G*\uff09\u5c0d\u6b64\u932f\u5408\u7269\u9032\u884c\u81ea\u7136\u5e03\u5c45\u5206\u6790\uff08natural population analysis\uff09\uff0c\u767c\u73fe\u5176\u4e2d\u7684\u787c\u5177\u6709\u8f03\u5c0f\u7684\u6b63\u96fb\u8377\uff08+0.36\uff09\uff0c\u800c\u5728\u82ef\u4e26\u54aa\u5511\u57fa\u7247\u6bb5\u7684\u78b3\u5177\u6709\u7684\u8ca0\u96fb\u8377\u70ba -0.65\uff1b\u6b64\u5916\uff0c\u4ee5\u81ea\u7136\u9375\u8ecc\u9053\u7406\u8ad6\u5206\u6790\u6b64\u932f\u5408\u7269\uff0c\u986f\u793a\u787c\u8207\u5169\u500b\u78b3\u539f\u5b50\u4e4b\u9593\u5b58\u5728 \u03c3- \u8207 \u03c0- \u9375\uff08\u5716\u4e8c (b)\uff09\uff0c\u9019\u8868\u793a\u540c\u78b3\u96d9\u78b3\u70ef\u7684\u7b2c\u4e8c\u5c0d\u5b64\u96fb\u5b50\u5c0d\u5728\u78b3\u8207\u787c\u539f\u5b50\u4e4b\u9593\u5171\u632f\uff3b8\uff3d<\/sup>\u3002<\/p>\n

\u70ba\u4e86\u589e\u52a0\u5361\u672c\u7684\u9aa8\u67b6\u591a\u6a23\u6027\uff0c\u672c\u5be6\u9a57\u5ba4\u767c\u5c55\u4e86\u4e00\u7a2e\u7c21\u55ae\u4e14\u66f4\u9032\u5316\u7684\u5408\u6210\u7b56\u7565\uff0c\u53ef\u4ee5\u5408\u6210\u5177\u6709\u975e\u5c0d\u7a31\u53d6\u4ee3\u57fa\u7684\u540c\u78b3\u96d9\u78b3\u70ef\u3002\u85c9\u7531\u53cd\u61c9\u6027\u7684\u7814\u7a76\uff0c\u767c\u73fe\u5b83\u5011\u53ef\u4ee5\u4f5c\u70ba\u6709\u6a5f\u50ac\u5316\u5291\uff0c\u50ac\u5316\u80fa\u985e\u5316\u5408\u7269\u8207\u4e8c\u6c27\u5316\u78b3\u9032\u884c\u7532\u57fa\u5316\u53cd\u61c9\uff0c\u9054\u6210\u56fa\u78b3\u50ac\u5316\u7684\u529f\u6548\uff08\u5716\u4e8c (c)\uff09\uff3b9\uff3d<\/sup>\u3002\u85c9\u7531\u540c\u78b3\u96d9\u78b3\u70ef\u8207\u5c0f\u5206\u5b50\u7684\u787c\u70f7\u548c\u77fd\u70f7\u9032\u884c\u6d3b\u5316\u53cd\u61c9\uff0c\u53ef\u4ee5\u89c0\u5bdf\u5230\u7684 1,2- \u52a0\u6210\u53cd\u61c9\u7684\u7522\u7269\uff0c\u7d50\u5408 X-ray \u55ae\u6676\u7e5e\u5c04\u7d50\u69cb\u8207\u7406\u8ad6\u8a08\u7b97\u5206\u6790\u5176\u9200\u932f\u5408\u7269\uff0c\u78ba\u5207\u7684\u8b49\u660e\u540c\u78b3\u96d9\u78b3\u70ef\u7684 \u03c0- \u96fb\u5b50\u63a5\u53d7\u80fd\u529b\uff3b10\uff3d<\/sup>\uff0c\u9019\u4e9b\u65b0\u767c\u73fe\u7684\u5316\u5b78\u7279\u5fb5\u5c0d\u65bc\u5c0f\u5206\u5b50\u7684\u6d3b\u5316\u53cd\u61c9\u8207\u300c\u53d7\u963b\u300d\u8def\u6613\u65af\u9178\u9e7c\u5c0d\uff08frustrated Lewis pair, FLP\uff09\u5177\u6709\u975e\u5e38\u76f8\u4f3c\u7684\u884c\u70ba\u6a21\u5f0f\u3002<\/p>\n

FLP \u662f\u4e00\u7a2e\u85c9\u7531\u7acb\u9ad4\u969c\u7919\u963b\u7d55\u8def\u6613\u65af\u9178\u8207\u8def\u6613\u65af\u9e7c\u7d50\u5408\u7684\u7279\u6b8a\u7d50\u69cb\uff0c\u5b83\u80fd\u5920\u626e\u6f14\u904e\u6e21\u91d1\u5c6c\u7684\u89d2\u8272\u9032\u884c\u6c2b\u6c23\u6d3b\u5316\u3001\u4e8c\u6c27\u5316\u78b3\u9084\u539f\u3001\u77fd\u6c2b\u5316\u3001\u787c\u57fa\u5316\u53ca\u80fa\u57fa\u5316\u7b49\u5c0f\u5206\u5b50\u6d3b\u5316\u53cd\u61c9\u3002\u61c9\u7528\u524d\u9762\u7684\u6982\u5ff5\uff0c\u5c07\u540c\u78b3\u96d9\u78b3\u70ef\u5206\u5b50\u7d50\u5408\u300c\u5171\u8abf\u7bc0\u5291\u300d\u82ef\u7532\u9187\uff08\u5e03\u4f96\u65af\u60d5\u9178\uff09\u53bb\u8abf\u63a7\u4e26\u6fc0\u6d3b\u672a\u6d3b\u5316\u7684\u8def\u6613\u65af\u9178\uff0c\u5f62\u6210\u6975\u70ba\u985e\u4f3c FLP \u4e14\u5f37\u6709\u529b\u7684\u50ac\u5316\u5291\uff0c\u5c07\u5176\u61c9\u7528\u65bc\u9187\u985e\u5316\u5408\u7269\u7684\u53bb\u6c2b\u77fd\u57fa\u5316\u53cd\u61c9\uff08dehydrosilylation\uff09\u3001\u7570\u6c30\u9178\u916f\u884d\u751f\u7269\u7684\u74b0\u4e09\u805a\u5408\u53cd\u61c9\uff08cyclotrimerization\uff09\u3001\u4e73\u9178\u4ea4\u916f\uff08L<\/em>-lactide, LA\uff09\u7684\u958b\u74b0\u805a\u5408\u53cd\u61c9\u53ca\u7532\u57fa\u4e19\u70ef\u9178\u7532\u916f\uff08methyl methacrylate, MMA\uff09\u7684\u805a\u5408\u53cd\u61c9\uff0c\u7686\u80fd\u5f97\u5230\u975e\u5e38\u512a\u7570\u7684\u53cd\u61c9\u7d50\u679c\u3002\u5728\u7814\u7a76\u904e\u7a0b\u4e2d\u6211\u5011\u4f7f\u7528 1<\/sup>H-1<\/sup>H NOESY NMR \u78ba\u8a8d\u4e86\u540c\u78b3\u96d9\u78b3\u70ef\u8207\u82ef\u7532\u9187\u4e4b\u9593\u7684\u4ea4\u4e92\u4f5c\u7528\uff0c\u4ee5 X-ray \u55ae\u6676\u7e5e\u5c04\u6280\u8853\u5c0d\u540c\u78b3\u96d9\u78b3\u70ef\u8207\u7570\u6c30\u9178\u916f\u884d\u751f\u7269\u53cd\u61c9\u4e4b\u4e2d\u9593\u9ad4\u9032\u884c\u7d50\u69cb\u5206\u6790\uff0c\u4e26\u8207\u5357\u4eac\u5de5\u696d\u5927\u5b78\u7684\u8d99\u8389\u8389\u6559\u6388\u9032\u884c\u570b\u969b\u5408\u4f5c\uff0c\u5229\u7528\u7406\u8ad6\u8a08\u7b97\u63a2\u8a0e\u74b0\u4e09\u805a\u5408\u53cd\u61c9\u7684\u53cd\u61c9\u6a5f\u5236\uff0c\u5f97\u77e5\u540c\u78b3\u96d9\u78b3\u70ef\u8207\u82ef\u7532\u9187\u4e4b\u9593\u7684\u4f5c\u7528\u5c0d\u53cd\u61c9\u6240\u9020\u6210\u7684\u5f71\u97ff\uff08\u5716\u4e8c (d)\uff09\uff3b11\uff3d<\/sup>\u3002<\/p>\n

\u70ba\u4e86\u64f4\u5c55\u5361\u672c\u7684\u591a\u6a23\u6027\u9aa8\u67b6\uff0c\u672c\u5be6\u9a57\u5ba4\u7a4d\u6975\u958b\u767c\u9257\u5f62\u5361\u672c\u914d\u4f4d\u57fa\uff0c\u897f\u5143 2015 \u5e74\u6210\u529f\u5408\u6210\u4e26\u767c\u8868\u4e09\u7259\u4e4b\u96d9\u5421\u5576\u540c\u78b3\u96d9\u78b3\u70ef\u914d\u4f4d\u57fa\uff0c\u4e26\u5229\u7528\u5176\u9200\u91d1\u5c6c\u932f\u5408\u7269\u50ac\u5316 Mizoroki-Heck \u53ca Suzuki-Miyaura \u4ea4\u53c9\u8026\u5408\u53cd\u61c9\uff3b12\uff3d<\/sup>\uff1b\u96a8\u5f8c\u7d50\u5408\u50b3\u7d71\u7684\u904e\u6e21\u91d1\u5c6c\u50ac\u5316\u5076\u806f\uff082e- \u904e\u7a0b\uff09\u548c\u5149\u6c27\u5316\u9084\u539f\u50ac\u5316\uff081e- \u904e\u7a0b\uff09\uff0c\u5728\u6eab\u548c\u7684\u53cd\u61c9\u689d\u4ef6\u4e0b\u5229\u7528\u53ef\u898b\u5149\u7167\u5c04\uff0c\u50ac\u5316\u4ea4\u53c9\u5076\u806f\u53cd\u61c9\u5f62\u6210 C-N \u9375\uff0c\u540c\u6642\u4e5f\u5229\u7528\u55ae\u4e00\u50ac\u5316\u5291\u5728\u5e38\u6eab\u689d\u4ef6\u4e0b\u9032\u884c\u6709\u6548\u7684\u4e00\u934b\u5316 C-H \u82b3\u57fa\u5316\u53cd\u61c9\uff08\u5716\u4e8c (e)\uff09\uff3b13\uff3d<\/sup>\u3002<\/p>\n

\u672c\u5be6\u9a57\u5ba4\u6700\u8fd1\u767c\u5c55\u53e6\u4e00\u985e\u55ae\u5421\u5576\u96d9\u5361\u672c\u7684\u9257\u5f62\u914d\u4f4d\u57fa\uff0c\u662f\u7b2c\u4e00\u500b\u7a69\u5b9a\u4e14\u53ef\u5206\u96e2\u4e26\u5177\u6709\u660e\u78ba\u6676\u9ad4\u7d50\u69cb\u7684\u6e38\u96e2\u96d9\u5361\u672c\u9aa8\u67b6\uff0c\u53ef\u4ee5\u5229\u7528\u5176\u9257\u5f62\u7d50\u69cb\u7a69\u5b9a\u55ae\u91d1\u5c6c Ni \u548c Pd \u7684\u932f\u5408\u7269\uff0c\u4e5f\u53ef\u4ee5\u5229\u7528\u5361\u672c\u7684\u7b2c\u4e8c\u5c0d\u5b64\u96fb\u5b50\u5c0d\u914d\u4f4d\u5176\u4ed6\u91d1\u5c6c\u932f\u5408\u7269\uff0c\u5f62\u6210\u7a69\u5b9a\u7684\u4e09\u6838\u7570\u91d1\u5c6c Au-Pd-Au\u3001 Au-NiAu \u548c Cu-Ni-Cu \u69cb\u5f62\u932f\u5408\u7269\u3002\u5229\u7528\u5148\u9032\u7684\u91cf\u5b50\u7406\u8ad6\u5206\u6790\u767c\u73fe\u91d1\u5c6c\u2014\u91d1\u5c6c\u76f8\u4e92\u4f5c\u7528\u529b\u592a\u5f31\uff0c\u7121\u6cd5\u5728\u7dad\u6301\u9019\u4e9b\u591a\u91d1\u5c6c\u914d\u7f6e\u4e0a\u767c\u63ee\u91cd\u8981\u4f5c\u7528\uff0c\u96d9\u5361\u672c\u9aa8\u67b6\u5167\u7684\u56db\u5c0d\u5b64\u96fb\u5b50\u5c0d\u624d\u662f\u591a\u91d1\u5c6c\u932f\u5408\u7269\u7a69\u5b9a\u6027\u7684\u4e3b\u8981\u8ca2\u737b\u8005\uff08\u5716\u4e8c (f)\uff09\uff3b14\uff3d<\/sup>\u3002<\/p>\n

 <\/p>\n

\"\u3010\u5c08\u6b04\u3011\u795e\u5947\u7684\u975e\u516b\u9685\u9ad4\u78b3\u914d\u4f4d\u57fa\"

\u25b2\u5716\u4e8c\uff1a(a) \u5361\u672c\u5316\u5408\u7269\u7684\u6f14\u9032\uff1b(b) \u4e0a\u5de6\uff1a\u5229\u7528\u81ea\u7136\u5e03\u5c45\u5206\u6790\u89e3\u91cb\u96d9\u967d\u96e2\u5b50\u787c\u6c2b\u932f\u5408\u7269\uff0c\u6578\u5b57\u8868\u793a\u932f\u5408\u7269\u7684\u787c\u539f\u5b50\u548c\u6700\u63a5\u8fd1\u787c\u7684\u78b3\u539f\u5b50\u4e4b\u96fb\u8377\u503c\u53ca\u82ef\u4e26\u54aa\u5511\u57fa\u7247\u6bb5\u7684\u96fb\u8377\u7e3d\u548c\u3002\u4e0b\uff1a\u5229\u7528\u81ea\u7136\u9375\u8ecc\u9053\u7406\u8ad6\uff08NBOs\uff09\u5206\u6790\u96d9\u967d\u96e2\u5b50\u787c\u6c2b\u932f\u5408\u7269\u7684\u787c\u8207\u78b3\u4e4b\u9593 \u03c3 \uff08\u5de6\uff09\u8207 \u03c0 \uff08\u53f3\uff09\u9375\u7684\u7d44\u6210\uff1b(c) \u5229\u7528 SN2<\/sub> \u53cd\u61c9\u7b56\u7565\u5408\u6210\u975e\u5c0d\u7a31\u540c\u78b3\u96d9\u78b3\u70ef\uff0c\u4e26\u61c9\u7528\u65bc CO2<\/sub> \u4e4b\u56fa\u78b3\u53cd\u61c9\uff1b(d) \u5229\u7528\u82ef\u7532\u9187\uff08\u5e03\u4f96\u65af\u60d5\u9178\uff09\u8abf\u63a7\u4e26\u6fc0\u6d3b\u672a\u6d3b\u5316\u7684\u8def\u6613\u65af\u9178\uff0c\u4f7f\u540c\u78b3\u96d9\u78b3\u70ef\u5177\u6709\u985e\u4f3c FLP \u7684\u53cd\u61c9\u6027\uff1b(e) \u5229\u7528\u55ae\u4e00\u50ac\u5316\u5291\u5728\u5e38\u6eab\u7167\u5149\u689d\u4ef6\u4e0b\u9032\u884c\u4e00\u934b\u5316 C-H \u82b3\u57fa\u5316\u53cd\u61c9\uff1b(f) \u7b2c\u4e00\u500b\u5408\u6210\u7684\u4e09\u7259\u96d9\u5361\u672c\u5316\u5408\u7269\u53ca\u5176\u6240\u5f62\u6210\u7684\u4e09\u91d1\u5c6c\u932f\u5408\u7269\u3002<\/p><\/div>\n

 <\/p>\n

\u540c\u78b3\u96d9\u78b3\u70ef\u662f\u8fd1\u5e74\u4f86\u65b0\u8208\u5d1b\u8d77\u7684\u5f37\u914d\u4f4d\u57fa\uff0c\u80fd\u5920\u7a69\u5b9a\u4e3b\u65cf\u5316\u5408\u7269\u53ca\u904e\u6e21\u91d1\u5c6c\u932f\u5408\u7269\uff0c\u751a\u81f3\u5f97\u5230\u5176\u4ed6\u914d\u4f4d\u57fa\u7121\u6cd5\u5f62\u6210\u7684\u932f\u5408\u7269\uff0c\u4e3b\u8981\u6b78\u56e0\u65bc\u5177\u6709\u5169\u5c0d\u5b64\u96fb\u5b50\u5c0d\u7684\u96f6\u50f9\u78b3\u4e2d\u5fc3\u3002\u7121\u8ad6\u662f\u76f4\u63a5\u61c9\u7528\u65bc\u6709\u6a5f\u50ac\u5316\u6216\u904e\u6e21\u91d1\u5c6c\u50ac\u5316\u53cd\u61c9\uff0c\u5927\u90fd\u80fd\u5920\u6709\u826f\u597d\u7684\u53cd\u61c9\u6027\uff0c\u5c24\u5176\u5728\u300c\u5171\u8abf\u7bc0\u5291\u300d\u82ef\u7532\u9187\u7684\u8abf\u63a7\u5be6\u9a57\u4e2d\uff0c\u540c\u78b3\u96d9\u78b3\u70ef\u5177\u6709\u6975\u70ba\u985e\u4f3c FLP \u7684\u53cd\u61c9\u884c\u70ba\uff0c\u4e5f\u8868\u73fe\u51fa\u4e0d\u4e9e\u65bc\u91d1\u5c6c\u50ac\u5316\u5291\u5728\u9ad8\u5206\u5b50\u805a\u5408\u3001\u5171\u805a\u5408\u7b49\u53cd\u61c9\u4e2d\u7684\u50ac\u5316\u80fd\u529b\u3002\u7814\u7a76\u5718\u968a\u9664\u4e86\u6301\u7e8c\u63a2\u8a0e\u6b64\u50ac\u5316\u6a5f\u5236\u5c0d\u5176\u4ed6\u985e\u578b\u5316\u5408\u7269\u7684\u53cd\u61c9\u7d50\u679c\u4e4b\u5916\uff0c\u540c\u6642\u4e5f\u5c07\u5be6\u9a57\u91cf\u7d1a\u64f4\u5927\uff0c\u4ee5\u5229\u65bc\u7814\u7a76\u6210\u679c\u5be6\u969b\u904b\u7528\u5728\u5de5\u696d\u88fd\u7a0b\u4e2d\u3002\u76f8\u4fe1\u5728\u4e0d\u4e45\u7684\u672a\u4f86\uff0c\u540c\u78b3\u96d9\u78b3\u70ef\u5c07\u80fd\u6210\u70ba\u5de5\u696d\u751f\u7522\u4e2d\u7684\u6709\u6a5f\u50ac\u5316\u5291\u4e3b\u6d41\uff0c\u5728\u7d93\u6fdf\u767c\u5c55\u7684\u524d\u63d0\u4e0b\u540c\u6642\u517c\u9867\u74b0\u5883\u4fdd\u8b77\uff0c\u8b93\u7d93\u6fdf\u767c\u5c55\u8207\u74b0\u5883\u53cb\u5584\u4e26\u80a9\u540c\u884c\u3002<\/p>\n

 <\/p>\n

\n

\u53c3\u8003\u8cc7\u6599<\/strong><\/p>\n

    \n
  1. (a) Li, Y.; Mondal, K. C.; Samuel, P. P.; Zhu, H.; Orben, C. M.; Panneerselvam, S.; Dittrich, B.; Schwederski, B.; Kaim, W.; Mondal, T.; Koley, D.; Roesky, H. W., C4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication. Angew. Chem., Int. Ed.<\/em> 2014<\/strong>, 53<\/em>, 4168\u22124172. (b) Wu, D.; Li, Y.; Ganguly, R.; Kinjo, R., Synthesis and structural characterization of a C4<\/sub> cumulene including 4-pyridylidene units, and its reactivity towards ammonia-borane. Chem. Commun.<\/em> 2014<\/strong>, 50<\/em>, 12378\u221212381. (c) Asay, M.; Donnadieu, B.; Schoeller, W. W.; Bertrand, G., Synthesis of Allenylidene Lithium and Silver Complexes, and Subsequent Transmetalation Reactions. Angew. Chem., Int. Ed.<\/em> 2009<\/strong>, 48<\/em>, 4796\u22124799. (d) Miyamoto, K.; Narita, S.; Masumoto, Y.; Hashishin, T.; Osawa, T.; Kimura, M.; Ochiai, M.; Uchiyama, M. Room-temperature chemical synthesis of C2<\/sub>. Nat. Commun.<\/em> 2020<\/strong>, 11<\/em>, 2134.<\/li>\n
  2. Leung, T.-F.; Jiang, D.; Wu, M.-C.; Xiao, D.; Ching, W.-M.; Yap, G. P. A.; Yang, T.; Zhao, L.; Ong, T.-G.; Frenking, G. Isolable dicarbon stabilized by a single phosphine ligand. Nat. Chem.<\/em> 2021<\/strong>, 13<\/em>, 89\u221293.<\/li>\n
  3. Wu, M.-C.; Liang, Y.-F.; Jurca, T.; Yap, G. P. A.; Leung, T.-F.; Ong, T.-G. Reactive Dicarbon as a Flexible Ligand for Transition-Metal Coordination and Catalysis. J. Am. Chem. Soc.<\/em> 2022<\/strong>, 144<\/em>, 12996\u221213005.<\/li>\n
  4. Ramirez, F.; Desai, N. B.; Hansen, B.; McKelvie, N. Hexaphenylcarbodiphosphorane, (C6<\/sub>H5<\/sub>)3<\/sub>PCP(C6<\/sub>H5<\/sub>)3<\/sub>. J. Am. Chem. Soc.<\/em> 1961<\/strong>, 83<\/em>, 3539-3540.<\/li>\n
  5. Tonner, R.; Frenking, G. C(NHC)2<\/sub>: divalent carbon(0) compounds with N-heterocyclic carbene ligands-theoretical evidence for a class of molecules with promising chemical properties. Angew. Chem., Int. Ed.<\/em> 2007<\/strong>, 46<\/em>, 8695\u22128698.<\/li>\n
  6. Dyker, C. A.; Lavallo, V.; Donnadieu, B.; Bertrand, G. Synthesis of an extremely bent acyclic allene (a “carbodicarbene”): a strong donor ligand. Angew. Chem., Int. Ed.<\/em> 2008<\/strong>, 47<\/em>, 3206\u22123209.<\/li>\n
  7. Chen, W.-C.; Hsu, Y.-C.; Lee, C.-Y.; Yap, G. P. A.; Ong T.-G. Synthetic Modification of Acyclic Bent Allenes (Carbodicarbenes) and Further Studies on Their Structural Implications and Reactivities. Organometallics<\/em> 2013<\/strong>, 32<\/em>, 2435\u22122442.<\/li>\n
  8. Chen, W.-C.; Lee, C.-Y.; Lin, B.-C.; Hsu, Y.-C.; Shen, J.-S.; Hsu, C.-P.; Yap, G. P. A.; Ong, T.-G. The Elusive Three-Coordinate Dicationic Hydrido Boron Complex. J. Am. Chem. Soc.<\/em> 2014<\/strong>, 136<\/em>, 914\u2212917.<\/li>\n
  9. Chen, W.-C.; Shen, J.-S.; Jurca, T.; Peng, C.-J.; Lin, Y.-H.; Wang, Y.-P.; Shih, W.-C.; Yap, G. P. A.; Ong, T.-G. Expanding the Ligand Framework Diversity of Carbodicarbenes and Direct Detection of Boron Activation in the Methylation of Amines with CO2<\/sub>. Angew. Chem., Int. Ed.<\/em> 2015<\/strong>, 54<\/em>, 15207\u221215212.<\/li>\n
  10. Chen, W.-C.; Shih, W.-C.; Jurca, T.; Zhao, L.; Andrada, D. M.; Peng, C.-J.; Chang, C.-C.; Liu, S.-k.; Wang, Y.-P.; Wen, Y.-S.; Yap, G. P. A.; Hsu, C.-P.; Frenking, G.; Ong, T.-G. Carbodicarbenes: Unexpected \u03c0-Accepting Ability during Reactivity with Small Molecules. J. Am. Chem. Soc.<\/em> 2017<\/strong>, 139<\/em>, 12830\u221212836.<\/li>\n
  11. Chan, Y.-C.; Bai, Y.; Chen, W.-C.; Chen, H.-Y.; Li, C.-Y.; Wu, Y.-Y.; Tseng, M.-C.; Yap, G. P. A.; Zhao, L.; Chen, H.-Y.; Ong, T.-G. Synergistic Catalysis by Br\u00f8nsted Acid\/Carbodicarbene Mimicking Frustrated Lewis Pair-Like Reactivity. Angew. Chem., Int. Ed.<\/em> 2021<\/strong>, 60<\/em>, 19949\u221219956.<\/li>\n
  12. Hsu, Y.-C.; Shen, J.-S.; Lin, B.-C.; Chen, W.-C.; Chan, Y.-T.; Ching, W.-M.; Yap, G. P. A.; Hsu, C.-P.; Ong, T.-G. Synthesis and Isolation of an Acyclic Tridentate Bis(pyridine)carbodicarbene and Studies on Its Structural Implications and Reactivities. Angew. Chem., Int. Ed.<\/em> 2015<\/strong>, 54<\/em>, 2420\u22122424.<\/li>\n
  13. Hsu, Y.-C.; Wang, V. C.-C.; Au-Yeung, K.-C.; Tsai, C.-Y.; Chang, C.-C.; Lin, B.-C.; Chan, Y.-T.; Hsu, C.-P.; Yap, G. P. A.; Jurca, T.; Ong T.-G. One-Pot Tandem Photoredox and Cross-Coupling Catalysis with a Single Palladium Carbodicarbene Complex. Angew. Chem., Int. Ed.<\/em> 2018<\/strong>, 57<\/em>, 4622\u20134626.<\/li>\n
  14. Aweke, B. S.; Yu, C.-H.; Zhi, M.; Chen, W.-C.; Yap, G. P. A.; Zhao, L.; Ong, T.-G. A Bis-(carbone) Pincer Ligand and Its Coordinative Behavior toward Multi-Metallic Configurations. Angew. Chem., Int. Ed.<\/em> 2022<\/strong>, 61<\/em>, e202201884.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

    \u78b3\uff08carbon\uff09\u662f\u4e00\u7a2e\u5728\u6211\u5011\u751f\u6d3b\u5468\u906d\u96a8\u8655\u53ef\u898b\u7684\u5316\u5b78\u5143\u7d20\uff0c\u5176\u5143\u7d20\u7b26\u865f\u70ba C\uff0c\u5b83\u4e5f\u662f\u6709\u6a5f\u548c\u7121\u6a5f\u5316\u5b78\u4e2d\u975e\u5e38\u91cd\u8981\u7684\u7d44\u6210\u4efd\u5b50\uff1b\u5728\u6709\u6a5f\u5316\u5b78\u9818\u57df\u88e1\u6240\u63a2\u8a0e\u7684\u6709\u6a5f\u5206\u5b50\uff0cC \u662f\u5fc5\u8981\u7684\u7d44\u6210\u5143\u7d20\uff0c<\/p>\n","protected":false},"author":1,"featured_media":32114,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_et_pb_use_builder":"","_et_pb_old_content":"","_et_gb_content_width":"","footnotes":""},"categories":[990,983],"tags":[],"acf":[],"_links":{"self":[{"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/posts\/32106"}],"collection":[{"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/comments?post=32106"}],"version-history":[{"count":1,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/posts\/32106\/revisions"}],"predecessor-version":[{"id":32839,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/posts\/32106\/revisions\/32839"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/media\/32114"}],"wp:attachment":[{"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/media?parent=32106"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/categories?post=32106"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/newsletter.sinica.edu.tw\/wp-json\/wp\/v2\/tags?post=32106"}],"curies":[{"name":"wp","href":"https:\/api.w.org\/{rel}","templated":true}]}}